Issue 18, 2001
From the journal:

Chemical Communications

1-Butyl-3-methylimidazolium cobalt tetracarbonyl [bmim][Co(CO)4]: a catalytically active organometallic ionic liquid

Richard J. C. Brown,a   Paul J. Dyson,*b   David J. Ellisb  and  Thomas Weltona  

* Corresponding authors

a Department of Chemistry, Imperial College of Science, Technology and Medicine, South Kensington, London, UK

b Department of Chemistry, The University of York, Heslington, York, UK
E-mail: pjd14@york.ac.uk

Abstract

An ambient temperature liquid transition metal carbonyl anion has been prepared in a metathesis reaction between [bmim]Cl ([bmim]+ = 1-butyl-3-methylimidazolium cation) and Na[Co(CO)4]; the ionic liquid catalyses the debromination of 2-bromoketones.

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Article information

DOI
https://doi.org/10.1039/B104601M
Article type
Communication
Submitted
25 May 2001
Accepted
01 Aug 2001
First published
03 Sep 2001

Chem. Commun., 2001, 1862-1863

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1-Butyl-3-methylimidazolium cobalt tetracarbonyl [bmim][Co(CO)4]: a catalytically active organometallic ionic liquid

R. J. C. Brown, P. J. Dyson, D. J. Ellis and T. Welton, Chem. Commun., 2001, 1862 DOI: 10.1039/B104601M

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