Issue 18, 2001
From the journal:

Chemical Communications

Addition of functional vinylzinc reagents to nitrones: synthesis of (E)-N-allylhydroxylamines and their rearrangement into (E)-O-allylhydroxylamines

Shashi Urvish Pandya,a   Corinne Garçon,a   Pierre Y. Chavant,a   Sandrine Pya  and  Yannick Vallée*a  

* Corresponding authors

a LEDSS, UMR 5616, Université J. Fourier, BP53, Grenoble CEDEX 9, France.
E-mail: Yannick.Vallee@ujf-grenoble.fr

Abstract

The vinylzinc reagents derived from hydrozirconation of alkynes and transmetallation add readily to nitrones to yield pure (E)-N-allylhydroxylamines; some of these rearrange into O-allylhydroxylamines.

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Article information

DOI
https://doi.org/10.1039/B104427N
Article type
Communication
Submitted
18 May 2001
Accepted
26 Jul 2001
First published
04 Sep 2001

Chem. Commun., 2001, 1806-1807

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Addition of functional vinylzinc reagents to nitrones: synthesis of (E)-N-allylhydroxylamines and their rearrangement into (E)-O-allylhydroxylamines

S. U. Pandya, C. Garçon, P. Y. Chavant, S. Py and Y. Vallée, Chem. Commun., 2001, 1806 DOI: 10.1039/B104427N

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