Issue 17, 2001
From the journal:

Chemical Communications

Efficient radical addition of tertiary amines to electron-deficient alkenes using semiconductors as photochemical sensitisers

Siniša Marinkovića  and  Norbert Hoffmann*a  

* Corresponding authors

a Laboratoire des Réactions Sélectives et Applications, UMR CNRS et Université de Reims Champagne-Ardenne, UFR Sciences, B.P. 1039, F-51687, Reims, Cedex 02, France.
E-mail: norbert.hoffmann@univ-reims.fr

Abstract

Tertiary amines can be added to electron-deficient alkenes with yields up to 98% in a radical chain reaction initiated by a photochemical electron transfer using inorganic semiconductors like TiO2 as sensitiser.

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Article information

DOI
https://doi.org/10.1039/B104387K
Article type
Communication
Submitted
18 May 2001
Accepted
09 Jul 2001
First published
03 Aug 2001

Chem. Commun., 2001, 1576-1578

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Efficient radical addition of tertiary amines to electron-deficient alkenes using semiconductors as photochemical sensitisers

S. Marinković and N. Hoffmann, Chem. Commun., 2001, 1576 DOI: 10.1039/B104387K

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