Issue 17, 2001
From the journal:

Chemical Communications

Non-catalytic and selective alkylation of phenol with propan-2-ol in supercritical water

Takafumi Sato,a   Gaku Sekiguchi,a   Tadafumi Adschiria  and  Kunio Arai*a  

* Corresponding authors

a Department of Chemical Engineering, Tohoku University, Aoba 07 Aramaki-Aza, Aoba-ku, Sendai, Japan.
E-mail: karai@arai.che.tohoku.ac.jp
Fax: +81-22-217-7246
Tel: +81-22-217-7245

Abstract

Phenol can be alkylated with propan-2-ol without catalyst in supercritical water at 673 K with mainly ortho substituted alkylphenols being obtained and alkylation reaction rate increasing with increasing water density.

Graphical abstract: Non-catalytic and selective alkylation of phenol with propan-2-ol in supercritical water

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Article information

DOI
https://doi.org/10.1039/B104184N
Article type
Communication
Submitted
14 May 2001
Accepted
28 Jun 2001
First published
25 Jul 2001

Chem. Commun., 2001, 1566-1567

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Non-catalytic and selective alkylation of phenol with propan-2-ol in supercritical water

T. Sato, G. Sekiguchi, T. Adschiri and K. Arai, Chem. Commun., 2001, 1566 DOI: 10.1039/B104184N

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