Novel octahedral tungsten sulfidocyanide cluster anion [W6S8(CN)6]6−Electronic supplementary information (ESI) available: Fig. S1: observed and simulated XRPD patterns for 1. Fig. S2: observed XRPD pattern for 2. Fig. S3: TGA for 1. See http://www.rsc.org/suppdata/cc/b1/b104161b/
Abstract
Novel tungsten octahedral sulfidocyanide cluster compounds Na6[W6S8(CN)6]·18DMSO 1 and K6[W6S8(CN)6] 2 have been synthesized and characterized by X-ray crystallography and NMR spectroscopy.