Issue 13, 2001

Zr(OtBu)4-catalysed synthesis of acetone aldol adducts and domino aldol-Tishchenko reactions with diacetone alcohol as enol equivalentDedicated to Professor David A. Evans on the occasion of his 60th birthday.

Abstract

Zr(OtBu)4 was found to be a potent catalyst for the synthesis of acetone aldol adducts with diacetone alcohol as enol equivalent and for domino aldol-Tishchenko reaction giving rise to 1,3-anti-diol monoesters with excellent diastereoselectivity.

Article information

Article type
Communication
Submitted
02 Apr 2001
Accepted
16 May 2001
First published
14 Jun 2001

Chem. Commun., 2001, 1218-1219

Zr(OtBu)4-catalysed synthesis of acetone aldol adducts and domino aldol-Tishchenko reactions with diacetone alcohol as enol equivalent

C. Schneider and M. Hansch, Chem. Commun., 2001, 1218 DOI: 10.1039/B102941J

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