Issue 15, 2001
From the journal:

Chemical Communications

Different positions of the formally isolobal moieties H+ and (AuPPh3)+ in N-(5-methoxyquinolyl-8)-2,4,6-trinitroaniline and its auration product

Lyudmila G. Kuz’mina,*a   Alexander A. Bagatur’yants,b   Andrei V. Churakova  and  Judith A. K. Howardc  

* Corresponding authors

a Institute of General and Inorganic Chemistry, Russian Acad. Sci., Leninskii pr. 31, Moscow, Russia.
E-mail: kuzmina@igic.ras.ru

b Center of Photochemistry, Russian Acad. Sci., Novator Str. 7a, Moscow, Russia.
E-mail: sasha@photonics.ru

c Department of Chemistry, University of Durham, South Road, Durham, UK
E-mail: j.a.k.howard@durham.ac.uk

Abstract

It has been shown by an X-ray crystallographic analysis of N-(triphenylphosphinegold)-N-(5-methoxyquinolyl-8)- 2,4,6-trinitroaniline 1 and quantum chemical calculations on N-(5-methoxyquinolyl-8)-2,4,6-trinitroaniline 2 that H+ and (AuPPh3)+ sub-units in 1 and 2 occupy different positions at the amine and quinoline nitrogen atoms, respectively.

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Article information

DOI
https://doi.org/10.1039/B102938J
Article type
Communication
Submitted
02 Apr 2001
Accepted
20 Jun 2001
First published
11 Jul 2001

Chem. Commun., 2001, 1394-1395

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Different positions of the formally isolobal moieties H+ and (AuPPh3)+ in N-(5-methoxyquinolyl-8)-2,4,6-trinitroaniline and its auration product

L. G. Kuz’mina, A. A. Bagatur’yants, A. V. Churakov and J. A. K. Howard, Chem. Commun., 2001, 1394 DOI: 10.1039/B102938J

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