Issue 16, 2001
From the journal:

Chemical Communications

First example of electroassisted biomimetic activation of molecular oxygen by a (salen)Mn epoxidation catalyst in a room-temperature ionic liquid

Laurent Gaillona  and  Fethi Bedioui*b  

* Corresponding authors

a Laboratoire d′Electrochimie et Chimie Analytique, UMR CNRS-ENSCP n° 7575, UPMC, Bat F., 4 place Jussieu, Paris cedex 05, France

b ENSCP, 11 rue Pierre et Marie Curie, Paris cedex 05, France.
E-mail: bedioui@ext.jussieu.fr

Abstract

A first example of electroassisted activation of molecular oxygen by Jacobsen′s epoxidation catalyst in an ionic liquid at room temperature has been achieved and showed the formation of the postulated high-valent manganese–oxo active intermediate.

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Article information

DOI
https://doi.org/10.1039/B102526K
Article type
Communication
Submitted
19 Mar 2001
Accepted
02 Jul 2001
First published
19 Jul 2001

Chem. Commun., 2001, 1458-1459

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First example of electroassisted biomimetic activation of molecular oxygen by a (salen)Mn epoxidation catalyst in a room-temperature ionic liquid

L. Gaillon and F. Bedioui, Chem. Commun., 2001, 1458 DOI: 10.1039/B102526K

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