Carbene transposition involving double dehydrogenation of an sp3 carbon

Joseph N. Coalter III; John C. Huffman; Kenneth G. Caulton

doi:10.1039/B102422C

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Carbene transposition involving double dehydrogenation of an sp³ carbonElectronic supplementary information (ESI) available: synthetic and spectroscopic data. Crystallographic data and selected bond lengths and angle for B. See http://www.rsc.org/suppdata/cc/b1/b102422c/

Joseph N. Coalter III,^a John C. Huffman^a and Kenneth G. Caulton*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry and Molecular Structure Center, Indiana University, Bloomington, IN 47405-7102, USA.
E-mail: caulton@indiana.edu

Abstract

Two benzylic hydrogens of 2,6-Me₂C₆H₃O⁻ coordinated to RuCl(PCy₃)₂(CHPh)⁺ are transferred to the benzylidene ligand, liberating toluene to form a new carbene which is covalently linked to the aryloxide ligand.

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/B102422C
Article type: Communication
Submitted: 14 Mar 2001
Accepted: 03 May 2001
First published: 07 Jun 2001

Download Citation

Chem. Commun., 2001, 1158-1159

Permissions

Request permissions

Carbene transposition involving double dehydrogenation of an sp³ carbon

J. N. Coalter III, J. C. Huffman and K. G. Caulton, Chem. Commun., 2001, 1158 DOI: 10.1039/B102422C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications