Issue 11, 2001

Photochemical generation of acetonitrile oxide via the C–N bond cleavage of 3-methyl-2-(4-nitrophenyl)-2H-azirine

Abstract

Acetonitrile oxide (2) is produced by the irradiation of the title azirine 1 in the presence of O2 in fluid solutions and in low-temperature matrices through the capture of the biradical 7 with O2, which is generated by the photochemical C–N bond cleavage of the azirine ring.

Article information

Article type
Communication
Submitted
13 Mar 2001
Accepted
24 Apr 2001
First published
15 May 2001

Chem. Commun., 2001, 1036-1037

Photochemical generation of acetonitrile oxide via the C–N bond cleavage of 3-methyl-2-(4-nitrophenyl)-2H-azirine

H. Inui and S. Murata, Chem. Commun., 2001, 1036 DOI: 10.1039/B102384P

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