Issue 11, 2001
From the journal:

Chemical Communications

Hydrogen bonding and CH/π interactions for the stabilization of biomimetic zinc complexes: first examples of X-ray characterized alcohol and amide adducts to a tetrahedral dicationic Zn center

Olivier Sénèque,a   Michel Giorgib  and  Olivia Reinaud*a  

* Corresponding authors

a Laboratoire de Chimie et Biochimie Pharmacologiques et Toxicologiques, CNRS UMR 8601, Université René Descartes, 45 rue des Saint-Pères, Paris cedex 06, France.
E-mail: reinaud@biomedicale.univ-paris5.fr

b Laboratoire de Cristallochimie, CNRS UMR 6517, Centre scientifique Saint-Jéome, av. Escadrille Normandie-Niemen, Marseille cedex 20, France

Abstract

X-Ray analysis of two biomimetic (N3ZnL)2+ complexes with L = ethanol and formamide revealed that hydrogen bonding and CH/π interactions between the guest ligand L and the calix[6]arene host structure play a key role in their stabilization.

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Article information

DOI
https://doi.org/10.1039/B102322P
Article type
Communication
Submitted
12 Mar 2001
Accepted
18 Apr 2001
First published
11 May 2001

Chem. Commun., 2001, 984-985

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Hydrogen bonding and CH/π interactions for the stabilization of biomimetic zinc complexes: first examples of X-ray characterized alcohol and amide adducts to a tetrahedral dicationic Zn center

O. Sénèque, M. Giorgi and O. Reinaud, Chem. Commun., 2001, 984 DOI: 10.1039/B102322P

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