Issue 10, 2001
From the journal:

Chemical Communications

2-Azabicyclo[2.2.1]hept-5-enes from 7-azabicyclo[2.2.1]heptadienes by tandem intermolecular radical addition—homoallylic radical rearrangement

David M. Hodgson,*a   Magnus W. P. Bebbingtona  and  Paul Willisb  

* Corresponding authors

a Dyson Perrins Laboratory, Department of Chemistry, University of Oxford, South Parks Road, Oxford, UK
E-mail: david.hodgson@chem.ox.ac.uk

b AstraZeneca, R&D Charnwood, Bakewell Road, Loughborough, UK

Abstract

Addition of thiols to 7-azabicyclo[2.2.1]heptadienes such as 16 leads exclusively to 7-thio-substituted 2-azabicyclo[2.2.1]-hept-5-enes 17 in good yields via tandem intermolecular radical addition—homoallylic radical rearrangement.

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Article information

DOI
https://doi.org/10.1039/B101984H
Article type
Communication
Submitted
02 Mar 2001
Accepted
02 Apr 2001
First published
20 Apr 2001

Chem. Commun., 2001, 889-890

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2-Azabicyclo[2.2.1]hept-5-enes from 7-azabicyclo[2.2.1]heptadienes by tandem intermolecular radical addition—homoallylic radical rearrangement

D. M. Hodgson, M. W. P. Bebbington and P. Willis, Chem. Commun., 2001, 889 DOI: 10.1039/B101984H

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