Synthesis of a 2D polymeric cluster {[NEt4][Mo2O2S6Cu6 I3- (4,4′-bipy)5]·MeOH·H2O} n with a significant improvement of optical limiting effectElectronic supplementary information (ESI) available: preparation, crystal structure details and nonlinear optical measurements for 3. See http://www.rsc.org/suppdata/cc/b1/b101929p/
Abstract
The self-assembly reaction of the monomeric nest-shaped
cluster
[NEt4]2[MoOS3Cu3I3]
1 or twin nest-shaped cluster
[NEt4]4[Mo2O2S6Cu
6I6] 2 with the bridging