Issue 9, 2001
From the journal:

Chemical Communications

A remarkable water-soluble (molecular) alloy with two tuneable solid-to-solid phase transitions

Dario Braga,*a   Gianna Cojazzi,b   Demis Paoluccia  and  Fabrizia Grepioni*c  

* Corresponding authors

a Department of Chemistry G. Ciamician, University of Bologna, Bologna, Italy.
E-mail: dbraga@ciam.unibo.it

b Centro CNR per la Fisica delle Macromolecole c/o Dipartimento di Chimica G. Ciamician, Università di Bologna, Via Selmi 2, Bologna, Italy

c Department of Chemistry, University of Sassari, Sassari, Italy.
E-mail: grepioni@ssmain.uniss.it

Abstract

The organometallic cations [(η5-C5H5)2Co]+ and [(η5-C5H5)2Fe]+ are fully miscible in the solid state and form the mixed crystalline material [(η5-C5H5)2Cox Fe1−x][PF6], which undergoes two fully reversible phase transitions that can be tuned by varying the molar ratio of the two cations; the water-soluble organometallic salt thus possesses the behaviour of a molecular alloy.

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Article information

DOI
https://doi.org/10.1039/B101749G
Article type
Communication
Submitted
23 Feb 2001
Accepted
20 Mar 2001
First published
17 Apr 2001

Chem. Commun., 2001, 803-804

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A remarkable water-soluble (molecular) alloy with two tuneable solid-to-solid phase transitions

D. Braga, G. Cojazzi, D. Paolucci and F. Grepioni, Chem. Commun., 2001, 803 DOI: 10.1039/B101749G

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