Issue 10, 2001
From the journal:

Chemical Communications

Extremely high trans selectivity of Ti-MWW in epoxidation of alkenes with hydrogen peroxide

Peng Wua  and  Takashi Tatsumi*a  

* Corresponding authors

a Division of Materials Science & Chemical Engineering, Faculty of Engineering, Yokohama National University, 79-5 Tokiwadai, Hodogaya-ku, Yokohama 240-8501, Japan.
E-mail: ttatsumi@ynu.ac.jp

Abstract

A novel titanosilicate with MWW topology, Ti-MWW, exhibits a behavior not observed on other titanosilicates such as TS-1, TS-2 and Ti-beta, in that it selectively epoxidizes trans isomers from a mixture of cis/trans alkenes with retention of stereochemistry.

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Article information

DOI
https://doi.org/10.1039/B101426I
Article type
Communication
Submitted
13 Feb 2001
Accepted
16 Mar 2001
First published
24 Apr 2001

Chem. Commun., 2001, 897-898

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Extremely high trans selectivity of Ti-MWW in epoxidation of alkenes with hydrogen peroxide

P. Wu and T. Tatsumi, Chem. Commun., 2001, 897 DOI: 10.1039/B101426I

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