Issue 18, 2001

Crystal engineering of microporous ‘Chinese-lantern’ compounds to improve their ability to reversibly adsorb sulfur dioxideElectronic supplementary information (ESI) available: full synthesis and crystal refinement details for 24. See http://www.rsc.org/suppdata/cc/b1/b101263k/

Abstract

Three new ‘Chinese lantern’ complexes [XMn(μ-dppO2)4MnX]2+2X·4MeOH·Me2CO [X = Cl, Br, I; dppO2 = 1,3-bis(diphenylphosphinoyl)propane], have been structurally characterised using single-crystal X-ray diffraction and shown to have increasing affinity for SO2 across the series Cl < Br < I via thermogravimetric measurements.

Supplementary files

Article information

Article type
Communication
Submitted
08 Feb 2001
Accepted
04 Jun 2001
First published
03 Sep 2001

Chem. Commun., 2001, 1764-1765

Crystal engineering of microporous ‘Chinese-lantern’ compounds to improve their ability to reversibly adsorb sulfur dioxide

W. I. Cross, S. M. Godfrey, C. A. McAuliffe and R. G. Pritchard, Chem. Commun., 2001, 1764 DOI: 10.1039/B101263K

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