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Issue 13, 2001
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Unique structural isomerism involving tetrazole and amide/azide derivatives of gallium

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Abstract

The reaction between {HC(MeCDippN)2}Ga: (Dipp = C6H3Pri2 -2,6) and N3SiMe3 afforded the tetrazole {HC(MeCDippN)2}[upper bond 1 start]GaN(SiMe3)NNN[upper bond 1 end](SiMe3) 1 and its amide/azide isomer {HC(MeCDippN)2}Ga(N3)N(SiMe3) 2 2 whose stabilities are due to the unique steric properties of the [HC(MeCDippN)2] ligand.

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Publication details

The article was received on 01 Jan 2001, accepted on 03 May 2001 and first published on 13 Jun 2001


Article type: Communication
DOI: 10.1039/B100466M
Citation: Chem. Commun., 2001,0, 1184-1185

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    Unique structural isomerism involving tetrazole and amide/azide derivatives of gallium

    N. J. Hardman and P. P. Power, Chem. Commun., 2001, 0, 1184
    DOI: 10.1039/B100466M

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