Issue 8, 2001
From the journal:

Chemical Communications

cis-Fused γ-lactones from simple precursors via  β-lactone rearrangements

T. Howard Black,†*a   Douglas C. Smith,‡a   Shane A. Eisenbeis,a   Karen A. Petersona  and  Mark S. Harmona  

* Corresponding authors

a Department of Chemistry, Eastern Illinois University, Charleston, IL, USA.
E-mail: thblack@eiu.edu

Abstract

cis-Fused bicyclic γ-lactones were prepared in a three step sequence, featuring the stereospecific rearrangement of spiro bicyclic β-lactones; the dependence of the β- to γ-lactone ring expansion on the relative stabilities of the intermediate carbocations was also investigated.

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Article information

DOI
https://doi.org/10.1039/B100261A
Article type
Communication
Submitted
02 Jan 2001
Accepted
03 Mar 2001
First published
03 Apr 2001

Chem. Commun., 2001, 753-754

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cis-Fused γ-lactones from simple precursors via  β-lactone rearrangements

T. H. Black, D. C. Smith, S. A. Eisenbeis, K. A. Peterson and M. S. Harmon, Chem. Commun., 2001, 753 DOI: 10.1039/B100261A

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