Issue 9, 2001
From the journal:

Chemical Communications

C–F bond activation of perfluoroalkenes by ruthenium phosphine hydride complexes: X-ray crystal structures of cis-Ru(dmpe)2F(F⋯HF) and [Ru(dcpe)2H]+[(CF3)2C[double bond, length half m-dash]C(O)CF2CF3]−

Matthew S. Kirkham,a   Mary F. Mahona  and  Michael K. Whittlesey*a  

* Corresponding authors

a Department of Chemistry, University of Bath, Claverton Down, Bath, UK
E-mail: m.k.whittlesey@bath.ac.uk

Abstract

The reaction of (CF3)2C[double bond, length half m-dash]C(F)CF2CF3 or CF3CF[double bond, length half m-dash]CF2 with Ru(dmpe)2H2 affords the bifluoride fluoride complex cis-Ru(dmpe)2F(F⋯HF), whereas reaction with Ru(dcpe)2H2 yields the cation [Ru(dcpe)2H]+ with [(CF3)2C[double bond, length half m-dash]C(O)CF2CF3] − as the anion.

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Article information

DOI
https://doi.org/10.1039/B009862K
Article type
Communication
Submitted
08 Dec 2000
Accepted
20 Mar 2001
First published
06 Apr 2001

Chem. Commun., 2001, 813-814

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C–F bond activation of perfluoroalkenes by ruthenium phosphine hydride complexes: X-ray crystal structures of cis-Ru(dmpe)2F(F⋯HF) and [Ru(dcpe)2H]+[(CF3)2C[double bond, length half m-dash]C(O)CF2CF3]−

M. S. Kirkham, M. F. Mahon and M. K. Whittlesey, Chem. Commun., 2001, 813 DOI: 10.1039/B009862K

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