Issue 4, 2001

Unprecedented C–H bond oxidative addition of the imidazolium cation to Pt0: a combined density functional analysis and experimental study

Abstract

Density functional studies predict that oxidative addition of an imidazolium salt to a Pt0 complex is an exothermic process, and consistent with this proposal, the reaction of the 1,3-dimethylimidazolium cation with Pt(PPh3)4 yields a hydrido–PtII carbene complex.

Article information

Article type
Communication
Submitted
04 Dec 2000
Accepted
17 Jan 2001
First published
07 Feb 2001

Chem. Commun., 2001, 355-356

Unprecedented C–H bond oxidative addition of the imidazolium cation to Pt0: a combined density functional analysis and experimental study

D. S. McGuinness, K. J. Cavell and B. F. Yates, Chem. Commun., 2001, 355 DOI: 10.1039/B009674L

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