Issue 4, 2001
From the journal:

Chemical Communications

Unprecedented C–H bond oxidative addition of the imidazolium cation to Pt0: a combined density functional analysis and experimental study

David S. McGuinness,a   Kingsley J. Cavell*b  and  Brian F. Yates*a  

* Corresponding authors

a School of Chemistry, University of Tasmania, GPO Box 252-75, Hobart, Tasmania, Australia

b Department of Chemistry, Cardiff University, PO Box 912, Cardiff, UK
E-mail: cavellkj@cf.ac.uk

Abstract

Density functional studies predict that oxidative addition of an imidazolium salt to a Pt0 complex is an exothermic process, and consistent with this proposal, the reaction of the 1,3-dimethylimidazolium cation with Pt(PPh3)4 yields a hydrido–PtII carbene complex.

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Article information

DOI
https://doi.org/10.1039/B009674L
Article type
Communication
Submitted
04 Dec 2000
Accepted
17 Jan 2001
First published
07 Feb 2001

Chem. Commun., 2001, 355-356

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Unprecedented C–H bond oxidative addition of the imidazolium cation to Pt0: a combined density functional analysis and experimental study

D. S. McGuinness, K. J. Cavell and B. F. Yates, Chem. Commun., 2001, 355 DOI: 10.1039/B009674L

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