Issue 4, 2001
From the journal:

Chemical Communications

Increased selectivity in hydroformylation reactions using dendrimer based

Loïc Ropartz,a   Russell E. Morris,a   Douglas F. Fosterb  and  David J. Cole-Hamilton*a  

* Corresponding authors

a School of Chemistry, University of St. Andrews, St. Andrews, Fife, Scotland, UK
E-mail: djc@st.andrews.ac.uk

b Catalyst Evaluation and Optimistaion Service (CATS), School of Chemistry, University of St. Andrews, St. Andrews, Fife, Scotland, UK

Abstract

Dendrimers based on polyhedral oligomeric silsesquioxanes (POSS) cores with 16 PPh2 arms give much higher linear selectivities (14∶1) than their small molecule analogues (3–4∶1) in the hydroformylation of oct-1-ene.

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Article information

DOI
https://doi.org/10.1039/B009574P
Article type
Communication
Submitted
29 Nov 2000
Accepted
11 Jan 2001
First published
08 Feb 2001

Chem. Commun., 2001, 361-362

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Increased selectivity in hydroformylation reactions using dendrimer based catalysts; a positive dendrimer effect

L. Ropartz, R. E. Morris, D. F. Foster and D. J. Cole-Hamilton, Chem. Commun., 2001, 361 DOI: 10.1039/B009574P

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