Issue 7, 2001
From the journal:

Chemical Communications

Synthesis, characterization and C–H activation reactivity of bis(ethylene) boratabenzene rhodium complexesElectronic supplementary information (ESI) available. Complete details for experimental procedures. See http://www.rsc.org/suppdata/cc/b0/b009246k/

David H. Woodmansee,a   Xianhui Bua  and  Guillermo C. Bazan*a  

* Corresponding authors

a Departments of Chemistry and Materials, University of California, Santa Barbara, CA, USA.
E-mail: bazan@chem.ucsb.edu

Abstract

Reaction of Li[C5H5B–Ph] with [RhCl(C2H4)2]2 gives [C5H5B–Ph]Rh(C2H4)2 1 in 91% yield; similarly, Li[C5H5B–NMe2] with [RhCl(C2H4)2]2 gives [C5H5B–NMe2]Rh(C2H4 )2 2 in 85% yield; single crystal X-ray analysis studies of 1 and 2 show a molecular geometry analogous to those of the Cp and Cp* complexes; the use of 1 and 2 in promoting alkane boration was evaluated against the activity of Cp*Rh(C2H4)2 3; the boratabenzene complexes 1 and 2 show faster initiation, but yield less thermally stable catalysts than 3.

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Supplementary files

Article information

DOI
https://doi.org/10.1039/B009246K
Article type
Communication
Submitted
16 Nov 2000
Accepted
13 Feb 2001
First published
13 Mar 2001

Chem. Commun., 2001, 619-620

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Synthesis, characterization and C–H activation reactivity of bis(ethylene) boratabenzene rhodium complexes

D. H. Woodmansee, X. Bu and G. C. Bazan, Chem. Commun., 2001, 619 DOI: 10.1039/B009246K

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