Hitherto non-isolable vinylketenes from the solid state photolysis of cis-1,2-dibenzoylalkene compounds have been isolated and characterized and their stabilities were found to be enhanced with the extent of steric congestion in the molecules.
Solid-state photolysis of sterically congested cis-1,2-dibenzoylalkenes: isolation and characterization of vinylketenes
M. Chanda, D. Maji and S. Lahiri, Chem. Commun., 2001, 543 DOI: 10.1039/B009013L
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