Issue 3, 2001

Nickel-catalysed acylstannylation of 1,2-dienes: synthesis and reactions of α-(acylmethyl)vinylstannanes

Abstract

Bis(cycloocta-1,5-diene)nickel was found to be an effective catalyst for the acylstannylation of 1,2-dienes to give a wide variety of α-(acylmethyl)vinylstannanes, which were transformed to variously substituted conjugated and unconjugated enones by carbon–carbon bond forming reactions.

Article information

Article type
Communication
Submitted
10 Oct 2000
Accepted
26 Oct 2000
First published
23 Jan 2001

Chem. Commun., 2001, 263-264

Nickel-catalysed acylstannylation of 1,2-dienes: synthesis and reactions of α-(acylmethyl)vinylstannanes

E. Shirakawa, Y. Nakao and T. Hiyama, Chem. Commun., 2001, 263 DOI: 10.1039/B008190F

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