Issue 1, 2001

Variable temperature electrochemistry as a powerful method for conformational investigations on the fluxional organometallic complex Mo(His-Nε-C2H4CO2 Me)(η-allyl)(CO)2 (His = Nδ, N,O-l-histidinate)Electronic supplementary information (ESI) available: analytical data for 2. See http://www.rsc.org/suppdata/cc/b0/b007822k

Abstract

Square-wave voltammograms of the complex Mo(His-Nε-C2H4CO 2Me)(η-allyl)(CO)2 (His = Nδ,N,O-L-histidinate) 2 recorded at variable temperatures establish the existence of two isomers in solution in both the reduced and the oxidized paramagnetic form of 2; a complete analysis yields thermodynamic parameters such as equilibrium constants, ΔG and ΔH for all species.

Supplementary files

Article information

Article type
Communication
Submitted
26 Sep 2000
Accepted
25 Oct 2000
First published
19 Dec 2000

Chem. Commun., 2001, 131-132

Variable temperature electrochemistry as a powerful method for conformational investigations on the fluxional organometallic complex Mo(His-Nε-C2H4CO2 Me)(η-allyl)(CO)2 (His = Nδ, N,O-L-histidinate)

D. R. van Staveren, E. Bothe, T. Weyhermüller and N. Metzler-Nolte, Chem. Commun., 2001, 131 DOI: 10.1039/B007822K

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