Structure and magnetic properties of a high-spinMn6IICrIII cluster containing cyanobridges and Mn centres capped by pentadentate ligands

Richard J. Parker; Leone Spiccia; Kevin J. Berry; Gary D. Fallon; Boujemaa Moubaraki; Keith S. Murray

doi:10.1039/B007113G

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Structure and magnetic properties of a high-spin Mn₆^IICr^III cluster containing cyano bridges and Mn centres capped by pentadentate ligands

Richard J. Parker,^a Leone Spiccia,*^a Kevin J. Berry,^b Gary D. Fallon,^a Boujemaa Moubaraki^a and Keith S. Murray^a

Author affiliations

* Corresponding authors

^a School of Chemistry, Monash University, PO Box 23, Victoria, Australia.
E-mail: leone.spiccia@sci.monash.edu.au

^b Westernport Secondary College, Victoria, Hastings, Australia

Abstract

The formation of an elaborate H-bonding network between heptanuclear cations, consisting of a hexacyanochromate capped by six [Mn(dmptacn)]²⁺ moieties, and hexacyanochromate counterions results in the assembly of novel 1-D chains with short-range ferrimagnetic behaviour occurring between the S = 27/2 clusters and S = 3/2 ions.

Download options Please wait...

Supplementary files

Crystal structure data TXT (25K)

Article information

DOI: https://doi.org/10.1039/B007113G
Article type: Communication
Submitted: 01 Sep 2000
Accepted: 11 Jan 2001
First published: 01 Feb 2001

Download Citation

Chem. Commun., 2001, 333-334

Permissions

Request permissions

Structure and magnetic properties of a high-spin Mn₆^IICr^III cluster containing cyano bridges and Mn centres capped by pentadentate ligands

R. J. Parker, L. Spiccia, K. J. Berry, G. D. Fallon, B. Moubaraki and K. S. Murray, Chem. Commun., 2001, 333 DOI: 10.1039/B007113G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications