Issue 1, 2001
From the journal:

Chemical Communications

Formation of an α-ketocarbene by photolysis of aqueous 2-bromophenol

Florent Bonnichon,a   Claire Richard*a  and  Gottfried Grabnerb  

* Corresponding authors

a Laboratoire de Photochimie Moléculaire et Macromoléculaire, UMR 6505, Université Blaise Pascal, Aubière Cedex, France.
E-mail: claire.richard@univ-bpclermont.fr;
Fax: Fax: +33 4 73 40 77 00
Tel: Tel: +33 4 73 40 71 42;

b Institut für Theoretische Chemie und Molekulare Strukturbiologie, Universität Wien, Althanstrasse 14, Wien, Austria

Abstract

The α-ketocarbene 2-oxocyclohexa-3,5-dienylidene (λmax = 360, 375 and 388 nm) is detected upon laser flash photolysis of 2-bromophenol in aqueous solution; its formation is confirmed by photoproduct studies.

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Article information

DOI
https://doi.org/10.1039/B006155G
Article type
Communication
Submitted
24 Jul 2000
Accepted
02 Nov 2000
First published
14 Dec 2000

Chem. Commun., 2001, 73-74

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Formation of an α-ketocarbene by photolysis of aqueous 2-bromophenol

F. Bonnichon, C. Richard and G. Grabner, Chem. Commun., 2001, 73 DOI: 10.1039/B006155G

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