Issue 3, 2001

Development of an analytical technique and stability evaluation of 143 C3–C12 volatile organic compounds in Summa® canisters by gas chromatography–mass spectrometry

Abstract

A technique using Summa® canisters with cryogenic preconcentration and gas chromatographic–mass spectrometric (GC-MS) detection was developed to determine 143 C3–C12 volatile organic compounds (VOCs) including alkanes, alkenes, aromatics and halohydrocarbons in ambient and indoor air. The method detection limits and practical quantification limits were sensitive at 0.02 and 0.10 ppbv, respectively, and the method precision and accuracy were also satisfactory. The stability of C3–C12 VOC standards at ppbv levels under elevated pressure in canisters was assessed over various time intervals (from 1 week to 4 months after preparation) and most of the compounds were found to be acceptably stable with a mean recovery of 85.6 ± 9.9% during the course of a 4-month study. However, a small fraction (approximately 6%) of the compounds, including two halohydrocarbons (bromotrichloromethane and benzyl chloride) and six alkenes (2-methylbuta-1,3-diene (isoprene), cis-4-methylpent-2-ene, cis-3-methylpent-2-ene, hept-1-ene, oct-1-ene and styrene) displayed relatively low recoveries in the range 34.6–67.9%. The loss of these compounds is most probably caused by their physical adherence to the active sites of the canister surface, chemical decomposition and/or reactions with other species. The results indicated that one must be cautious in attempting to measure these compounds owing to their instability in canisters. Overall, this analytical technique, which has been used for the determination of the VOCs under study in the toxic air pollutant monitoring network administered by the HKSAR Government, was amenable to the measurement of airborne VOCs collected both outside and inside a semi-confined car park in the present study.

Article information

Article type
Paper
Submitted
30 Oct 2000
Accepted
02 Jan 2001

Analyst, 2001,126, 310-321

Development of an analytical technique and stability evaluation of 143 C3–C12 volatile organic compounds in Summa® canisters by gas chromatographymass spectrometry

D. Wai-mei Sin, Y. Wong, W. Sham and D. Wang, Analyst, 2001, 126, 310 DOI: 10.1039/B008746G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements