Issue 11, 2000

Dynamic and stimulated nuclear polarisation in photochemical radical reactions

Abstract

Highly sensitive time-resolved magnetic resonance techniques based on the effect of variable radio-frequency and switched constant magnetic fields on the nuclear polarisation of diamagnetic products of radical reactions are considered. The applications of these methods to the investigation of short-lived radical intermediates (radical pairs, biradicals, free radicals and radical ions) formed in photochemical reactions in homogeneous and molecular-organised media are discussed. The bibliography includes 148 references.

Article information

Article type
Paper

Russ. Chem. Rev., 2000,69, 925-945

Dynamic and stimulated nuclear polarisation in photochemical radical reactions

E. G. Bagryanskaya and R. Z. Sagdeev, Russ. Chem. Rev., 2000, 69, 925 DOI: 10.1070/RC2000v069n11ABEH000599

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