Kinetics and mechanism of the aminolysis of aryl phenyldithioacetates in acetonitrile
Abstract
The aminolysis reactions of Z-aryl phenyldithioacetates (C6H5CH2C(S)SC6H4Z) with benzylamines (XC6H4CH2NH2) are investigated in
‡ ≈ 3 kcal mol−1) together with large negative
‡ = −37 to −53 e.u.) are consistent with concurrent