Issue 5, 2000
From the journal:

Journal of the Chemical Society, Perkin Transactions 2

Electron paramagnetic resonance and cyclic voltammetry of new alkylsulfanyl pyrroles. Models of stable radical cations

Victor M. Domingo,a   Enrique Brillas,b   Carlos Alemánc  and  Luis Juliá*a  

* Corresponding authors

a Departament de Química Orgànica Biològica, Institut d’Investigacions Químiques i Ambientals de Barcelona (CSIC), Jordi Girona 18-26, Barcelona, Spain

b Departament de Química Física, Universitat de Barcelona, Diagonal 647, Barcelona, Spain

c Departament d’Enginyeria Química, ETSEIB, Universitat Politècnica de Catalunya (UPC), Diagonal 647, Spain

Abstract

β-Functionalization with alkylsulfanyl groups in pyrroles contributes to stabilizing their radical cations by a mesomeric effect, as demonstrated by the presence of a reversible redox pair in their cyclic voltammetry diagrams and, when they are chemically oxidized, the detection of strong signals in electron paramagnetic resonance (EPR) spectroscopy.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/B002478N
Article type
Communication
Submitted
28 Mar 2000
Accepted
28 Mar 2000
First published
17 Apr 2000

J. Chem. Soc., Perkin Trans. 2, 2000, 905-906

Permissions

Request permissions

Electron paramagnetic resonance and cyclic voltammetry of new alkylsulfanyl pyrroles. Models of stable radical cations

V. M. Domingo, E. Brillas, C. Alemán and L. Juliá, J. Chem. Soc., Perkin Trans. 2, 2000, 905 DOI: 10.1039/B002478N

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements