Issue 9, 2000
From the journal:

Journal of the Chemical Society, Perkin Transactions 2

Photochemical transformations of matrix-isolated cycloalkyl nitrites †

Dorota Puchowicz,a   Jan Adamusa  and  Jerzy Gębicki*a  

* Corresponding authors

a Institute of Applied Radiation Chemistry, Technical University, Lodz, Poland

Abstract

Photochemical transformations of cycloalkyl nitrites isolated in argon matrices have been studied. In the case of cyclohexyl, cycloheptyl and cyclooctyl nitrites complexes of HNO with the corresponding cycloalkyl ketones were formed. Photochemical irradiation of cyclobutyl nitrite resulted in the formation of 4-nitrosobutanal as the major product. Under similar conditions irradiation of cyclopentyl nitrite gave a mixture of 5-nitrosocyclopentanal and the complex of cyclopentanone and HNO.

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Article information

DOI
https://doi.org/10.1039/B002405H
Article type
Paper
Submitted
27 Mar 2000
Accepted
07 Jun 2000
First published
27 Jul 2000

J. Chem. Soc., Perkin Trans. 2, 2000, 1942-1945

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Photochemical transformations of matrix-isolated cycloalkyl nitrites

D. Puchowicz, J. Adamus and J. Gębicki, J. Chem. Soc., Perkin Trans. 2, 2000, 1942 DOI: 10.1039/B002405H

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