Jump to main content
Jump to site search
Access to RSC content Close the message box

Continue to access RSC content when you are not at your institution. Follow our step-by-step guide.


Issue 22, 2000
Previous Article Next Article

Palladium catalysed cross-coupling of (fluoroarene)tricarbonylchromium(0) complexes

Author affiliations

Abstract

(Fluoroarene)tricarbonylchromium(0) complexes were found to undergo Suzuki and Stille cross-coupling reactions to form functionalised biaryl and styrene complexes in up to 87 and 52% yields, respectively. The Suzuki reactions were optimal with dipalladium tris(dibenzylideneacetone)–trimethylphosphine–caesium carbonate in DME at reflux. The Stille reactions were optimal with dipalladium tris(dibenzylideneacetone)–trimethylphosphine–caesium fluoride in DME at reflux and neither was adversely affected by a methoxy group on the complexed ring. The Suzuki reaction tolerated a chloro group on the arylboronic acid ring but not a bromo group.

Back to tab navigation

Article information


Submitted
11 Aug 2000
Accepted
29 Aug 2000
First published
31 Oct 2000

J. Chem. Soc., Perkin Trans. 1, 2000, 3808-3814
Article type
Paper

Palladium catalysed cross-coupling of (fluoroarene)tricarbonylchromium(0) complexes

R. Wilhelm and D. A. Widdowson, J. Chem. Soc., Perkin Trans. 1, 2000, 3808
DOI: 10.1039/B006576P

Search articles by author

Spotlight

Advertisements