Issue 20, 2000
From the journal:

Journal of the Chemical Society, Perkin Transactions 1

New heteroditopic, linked macrocyclic systems derived from selectively protected N2S2-, N3O2- and N4-donor macrocycles

Jy D. Chartres,a   Andrew M. Groth,a   Leonard F. Lindoy,*b   Mark P. Loweb  and  George V. Meehan*a  

* Corresponding authors

a School of Biomedical and Molecular Sciences, James Cook University, Townsville, Queensland, Australia

b School of Chemistry, University of Sydney, New South Wales, Australia

Abstract

The use of selectively tert-butoxycarbonyl protected derivatives of 1,9-dithia-5,13-diazacyclohexadecane 1, 1,7-dithia-4,11-diazacyclotetradecane 2, 1,4,8,11-tetraazacyclotetradecane 3 and 2,5-dioxa-8,11,14-triaza-1,6(1,2)-dibenzenacyclopentadecaphane 4 has enabled the efficient synthesis of new linked heteroditopic macrocyclic systems incorporating combinations of N2S2- and N4- or N3O2-donor sites. Incorporation of two types of binding sites in the respective products makes them suitable candidates for the synthesis of a range of mixed-metal, di- and oligo-nuclear metal complexes.

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Article information

DOI
https://doi.org/10.1039/B004797J
Article type
Paper
Submitted
15 Jun 2000
Accepted
10 Aug 2000
First published
28 Sep 2000

J. Chem. Soc., Perkin Trans. 1, 2000, 3444-3450

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New heteroditopic, linked macrocyclic systems derived from selectively protected N2S2-, N3O2- and N4-donor macrocycles

J. D. Chartres, A. M. Groth, L. F. Lindoy, M. P. Lowe and G. V. Meehan, J. Chem. Soc., Perkin Trans. 1, 2000, 3444 DOI: 10.1039/B004797J

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