Issue 11, 2000
From the journal:

Journal of the Chemical Society, Perkin Transactions 1

High valence vanadium complex promoted selective rearrangement of epoxides to aldehydes or ketones

Fernando Martínez,a   Carmen del Campoa  and  Emilio F. Llama*a  

* Corresponding authors

a Department of Organic and Pharmaceutical Chemistry, Faculty of Pharmacy, University Complutense of Madrid, Madrid, Spain

Abstract

High valence vanadium complexes induce the selective ring opening of epoxides. The monosubstituted epoxides are isomerized with complete regioselectivity each forming a single carbonyl compound exclusively. Likewise a highly regioselective isomerization of 1,1-disubstituted or 1,1,2-trisubstituted epoxides was observed in all reactions.

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Article information

DOI
https://doi.org/10.1039/B000965M
Article type
Paper
Submitted
03 Feb 2000
Accepted
17 Mar 2000
First published
05 May 2000

J. Chem. Soc., Perkin Trans. 1, 2000, 1749-1751

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High valence vanadium complex promoted selective rearrangement of epoxides to aldehydes or ketones

F. Martínez, C. del Campo and E. F. Llama, J. Chem. Soc., Perkin Trans. 1, 2000, 1749 DOI: 10.1039/B000965M

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