Issue 10, 2000
From the journal:

Journal of the Chemical Society, Perkin Transactions 1

Free radical chemistry. Part 10.1 Addition of acyclic and cyclic alkanes to hexafluoropropene

Richard D. Chambers,*a   Robert W. Fuss,a   Robert C. H. Spink,a   Martin P. Greenhall,b   Alan M. Kenwright,ac   Andrei S. Batsanovad  and  Judith A. K. Howardad  

* Corresponding authors

a Department of Chemistry, University of Durham, South Road, Durham, UK

b F2 Chemicals, Lea Lane, Lea Town, Preston, Lancashire, UK

c NMR Service, University of Durham, South Road, Durham, UK

d Crystallographic Unit, University of Durham, South Road, Durham, UK

Abstract

γ-Ray or peroxide initiated reactions of acyclic and cyclic alkanes with hexafluoropropene are described. A variety of perfluorocarbons and polyfluorinated alkenes, di-enes and a tetra-ene were synthesised from these polyfluoroalkylated alkanes. Elimination of hydrogen fluoride gives fluorinated alkenes, with unusual kinetic control of product formation and further fluorinations gave novel perfluorocarbons. X-Ray crystallography established structures of some isomers and NMR spectroscopy was used principally to establish the structures of others.

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Article information

DOI
https://doi.org/10.1039/A909777E
Article type
Paper
Submitted
13 Dec 1999
Accepted
08 Mar 2000
First published
25 Apr 2000

J. Chem. Soc., Perkin Trans. 1, 2000, 1623-1638

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Free radical chemistry. Part 10. Addition of acyclic and cyclic alkanes to hexafluoropropene

R. D. Chambers, R. W. Fuss, R. C. H. Spink, M. P. Greenhall, A. M. Kenwright, A. S. Batsanov and J. A. K. Howard, J. Chem. Soc., Perkin Trans. 1, 2000, 1623 DOI: 10.1039/A909777E

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