The self-assembly of zinc(II) porphyrins bearing a pyrazole substituent are reported. 1H NMR, UV/Vis and VPO measurements indicate the formation of a cyclic trimer of zinc(II) pyrazol-4-ylporphyrin and a tetramer of zinc(II) 3,5-dimethypyrazol-4-ylporphyrin by mutual coordination.
C. Ikeda, N. Nagahara, N. Yoshioka and H. Inoue, New J. Chem., 2000, 24, 897 DOI: 10.1039/B006371L
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