First crystal structure of a Tb3+ complex derived from an aromatic hydroxamate ligand: sensitized luminescence properties

Christine Tedeschi; Claude Picard; Joëlle Azéma; Bruno Donnadieu; Pierre Tisnès

doi:10.1039/B004288I

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

First crystal structure of a Tb³⁺ complex derived from an aromatic hydroxamate ligand: sensitized luminescence properties

Christine Tedeschi,^a Claude Picard,*^a Joëlle Azéma,^a Bruno Donnadieu^b and Pierre Tisnès^a

Author affiliations

* Corresponding authors

^a Laboratoire de Synthèse et Physicochimie de Molécules d'Intérêt Biologique (CNRS UMR 5068), Uniersité Paul Sabatier, 118, route de Narbonne, Toulouse cedex 04, France
E-mail: picard@iris.ups-tlse.fr

^b Laboratoire de Chimie de Coordination, 205 route de Narbonne, Toulouse cedex 04, France

Abstract

The neutral terbium complex [Tb(op)₃]·3H₂O derived from the 1-hydroxy-2(1H)-pyridinone ligand displays a good luminescent quantum yield (Φ=0.41 in MeOD solution), due to an efficient energy transfer through the hydroxamate linkage. The coordination properties of the hydroxamate functionality were established by X-ray analysis.

Download options Please wait...

Supplementary files

Crystal structure data TXT (17K)

Article information

DOI: https://doi.org/10.1039/B004288I
Article type: Letter
Submitted: 29 May 2000
Accepted: 10 Jul 2000
First published: 19 Sep 2000

Download Citation

New J. Chem., 2000,24, 735-737

Permissions

Request permissions

First crystal structure of a Tb³⁺ complex derived from an aromatic hydroxamate ligand: sensitized luminescence properties

C. Tedeschi, C. Picard, J. Azéma, B. Donnadieu and P. Tisnès, New J. Chem., 2000, 24, 735 DOI: 10.1039/B004288I

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

New Journal of Chemistry

First crystal structure of a Tb³⁺ complex derived from an aromatic hydroxamate ligand: sensitized luminescence properties

Abstract

Supplementary files

Article information

Download Citation

Permissions

First crystal structure of a Tb³⁺ complex derived from an aromatic hydroxamate ligand: sensitized luminescence properties

Social activity

Search articles by author

Spotlight

Advertisements