The catalytic oxidation of cyclohexanone to caprolactone using hexagonal mesoporous silica supported SbF3

Arnold Lambert; Duncan J. Macquarrie; Graham Carr; James H. Clark

doi:10.1039/B003161P

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The catalytic oxidation of cyclohexanone to caprolactone using hexagonal mesoporous silica supported SbF₃†

Arnold Lambert,^a Duncan J. Macquarrie,^a Graham Carr^b and James H. Clark^a

Author affiliations

^a Clean Technology Centre, Department of Chemistry, Uniersity of York, Heslington, York, UK

^b Solay Interox Ltd, Baronet Rd, Warrington, Cheshire, UK

Abstract

The solid acid catalyst SbF₃ supported on hexagonal mesoporous silica is an active and reasonably selective catalyst for the oxidation of cyclohexanone to caprolactone using hydrogen peroxide.

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Article information

DOI: https://doi.org/10.1039/B003161P
Article type: Letter
Submitted: 14 Apr 2000
Accepted: 03 May 2000
First published: 14 Jun 2000

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New J. Chem., 2000,24, 485-488

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The catalytic oxidation of cyclohexanone to caprolactone using hexagonal mesoporous silica supported SbF₃

A. Lambert, D. J. Macquarrie, G. Carr and J. H. Clark, New J. Chem., 2000, 24, 485 DOI: 10.1039/B003161P

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New Journal of Chemistry