Thermolysis of a free radical initiator in solutions of hydrogen donor solvents such as cyclohexane, 1,4-dioxane and methyl isobutyrate, generated radicals by hydrogen abstraction of the solvent that were capable of adding to the unsaturated bond of 4,5-ethylenic peroxyketals. The adduct radical obtained led to 2-alkoxytetrahydrofuran by an SHi on the O–O bond.
F. Ramon, M. Degueil-Castaing, M. Bevilacqua and B. Maillard, New J. Chem., 2000, 24, 209 DOI: 10.1039/A909434B
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