Issue 6, 2000

The kinetics of solvolysis of p-nitrophenyl bis(chloromethyl)phosphinate in a micellar solution of sodium dodecyl sulfate in ethylene glycol: catalysis by metal ions

Abstract

A 30-fold acceleration of the title reaction due to an increase in the activation entropy and activation enthalpy in the micellar pseudophase compared to ethylene glycol was found; Mg2+, Zn2+ and La3+ ions accelerate the solvolysis by factors of 5, 8 and 20, respectively.

Article information

Article type
Paper

Mendeleev Commun., 2000,10, 241-243

The kinetics of solvolysis of p-nitrophenyl bis(chloromethyl)phosphinate in a micellar solution of sodium dodecyl sulfate in ethylene glycol: catalysis by metal ions

L. Y. Zakharova, F. G. Valeeva, L. A. Kudryavtseva and A. I. Konovalov, Mendeleev Commun., 2000, 10, 241 DOI: 10.1070/MC2000v010n06ABEH001337

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