A mechanism of mutual diastereomeric transformations in the series of 3-cyano-2-oxo-1,2-thiaphosphorinanes was suggested, which is based on the eliminationattachment of a rather acidic hydrogen atom at the 3-position of the heterocycle.
I. L. Odinets, N. M. Vinogradova, K. A. Lyssenko, M. Y. Antipin and T. A. Mastryukova, Mendeleev Commun., 2000, 10, 216 DOI: 10.1070/MC2000v010n06ABEH001378
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