Issue 3, 2000

Chirality-directed self-assembling of long-chain dialkyl 3,7-diazabicyclo[3.3.1]nonane-2,6-dione-1,5-dicarboxylates

Abstract

Dihexyl and didodecyl 3,7-diazabicyclo[3.3.1]nonane-2,6-dione-1,5-dicarboxylates 4a,b were synthesised, and the self-assembling of the molecules of strictly alternating configurations was observed in a crystal of bis-lactam 4b, which resulted in formation of H-bonded heterochiral polymer tapes of a diagonal zigzag type combined into monomolecular layers separated by hydrophobic groups.

Article information

Article type
Paper

Mendeleev Commun., 2000,10, 106-108

Chirality-directed self-assembling of long-chain dialkyl 3,7-diazabicyclo[3.3.1]nonane-2,6-dione-1,5-dicarboxylates

R. G. Kostyanovsky, K. A. Lyssenko, I. A. Bronzova, O. N. Krutius, Y. A. Strelenko and A. A. Korlyukov, Mendeleev Commun., 2000, 10, 106 DOI: 10.1070/MC2000v010n03ABEH001294

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