Issue 3, 2000
From the journal:

Journal of Materials Chemistry

S. Le Moustarder,*a   P. Hudhomme,a   C. Durand,a   N. Mercier,a   M. T. Azcondo,b   P. Delhaes,b   A. Rioua  and  A. Gorguesa  

* Corresponding authors

a Laboratoire Ingénierie Moléculaire et Matériaux Organiques, UMR CNRS 6501, Université d'Angers, 2 Bd Lavoisier, Angers, France
E-mail: lemousta@univ-angers.fr

b Centre de Recherche Paul Pascal CNRS, avenue Albert Schweitzer, Pessac, France
E-mail: delhaes@axpp.crpp.u-bordeaux.fr

Abstract

The X-ray crystal structures and physical characterizations of the first radical cation salts obtained from the symmetrical S-position isomer of bis(ethylenedithio)tetrathiafulvalene (BEDT-TTF), are presented in this work. The unusual feature of this new π-donor D1, involved in the described salts (D1)3·(ClO4)2, (D1)3·(BF4)2 and D1·Cu(SCN)2, is the presence of two disulfide bridges, allowing weak intermolecular S⋯S interactions. The influence of these outer sulfur atoms on the network of related materials is also discussed in relation to the first physical characterizations which have been carried out.

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Article information

DOI
https://doi.org/10.1039/A908843A
Article type
Paper
Submitted
08 Nov 1999
Accepted
06 Jan 2000
First published
14 Feb 2000

J. Mater. Chem., 2000,10, 617-623

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First radical cation salts from the symmetrical outer S-position isomer of BEDT-TTF

S. Le Moustarder, P. Hudhomme, C. Durand, N. Mercier, M. T. Azcondo, P. Delhaes, A. Riou and A. Gorgues, J. Mater. Chem., 2000, 10, 617 DOI: 10.1039/A908843A

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