Issue 5, 2000

Abstract

Organochalcogenido-bridged dimeric 2-methylallylpalladium complexes of the type [Pd2(μ-ER)23-C4H7)2] (1) [ER = SBut (1a), SPh (1b), SC6F5 (1c), SePh (1d), TePh (1e)] have been prepared. The structure of the SBut bridged complex has been established by single crystal X-ray diffraction analysis. The four-membered Pd2S2 ring adopts a non-planar conformation with the two η3-2-MeC3H43-C4H7) in a syn configuration. The thermal behaviour of these complexes has been investigated by thermogravimetric analysis. These complexes yield Pd4E (E = S or Se) or Pd3Te2 at moderately low temperatures.

Supplementary files

Article information

Article type
Paper
Submitted
11 Oct 1999
Accepted
15 Feb 2000
First published
04 Apr 2000

J. Mater. Chem., 2000,10, 1121-1124

Organochalcogenido-bridged dimeric 2-methylallylpalladium complexes: synthesis, structure and their transformation into palladium chalcogenides

A. Singhal, V. K. Jain, R. Mishra and B. Varghese, J. Mater. Chem., 2000, 10, 1121 DOI: 10.1039/A908133J

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