Issue 2, 2000
From the journal:

Journal of Materials Chemistry

Chantal Brouca-Cabarrecq*a  and  Alain Mossetb  

* Corresponding authors

a Centre d'Elaboration des Matériaux et d'Etudes Structurales du CNRS, 29 rue Jeanne Marvig, Toulouse Cedex, France
E-mail: brouca@cemes.fr

b Laboratoire de Cristallographie, CNRS, 25 avenue des Martyrs, Grenoble Cedex 09, France

Abstract

The synthesis and the structure of two new gallium phosphates [NH3(CH2)3NH3]Ga3(PO4)3(OH)2·H2O (GaP1) space group Pcab, a = 10.043(3), b = 15.989(4), c = 18.308(6) Å and [NH2(CH2)3NH2]Ga3(PO4)3(H2O) (GaP2) space group Pbc21, a = 8.903(3), b = 9.697(3), c = 16.326(7) Å are presented. The syntheses were realised under hydrothermal conditions at 200 °C in the system Ga2O3–H3PO4–1,3-diaminopropane–H2O. These two compounds crystallise with a 3D-framework, with localised channels. In the GaP2 structure, 1,3-diaminopropane (1,3-DAP) is, unusually, coordinated to a gallium atom.

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Article information

DOI
https://doi.org/10.1039/A905099J
Article type
Paper
Submitted
25 Jun 1999
Accepted
10 Nov 1999
First published
14 Jan 2000

J. Mater. Chem., 2000,10, 445-450

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New potential open-framework materials in gallophosphate systems. Preparation and crystal structure of [NH3(CH2)3NH3]Ga3(PO4)3(OH)2·H2O and [NH2(CH2)3NH2]Ga3(PO4)3(H2O)

C. Brouca-Cabarrecq and A. Mosset, J. Mater. Chem., 2000, 10, 445 DOI: 10.1039/A905099J

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