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Issue 15, 2000
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Simple linear-chain cobalt phosphates

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Two simple one-dimensional cobalt phosphates containing linear chains of corner-shared 4-membered rings have been synthesized hydrothermally by the reaction between amine phosphates and cobalt(II) ions under non-aqueous conditions. The linear chains are held together by hydrogen bond interactions involving the hydrogens of the amine and the framework oxygens. The two cobalt phosphates reported are the first linear chain compounds discovered in the family of open-framework transition metal phosphates.

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The article was received on 04 Apr 2000, accepted on 13 Jun 2000 and first published on 13 Jul 2000

Article type: Paper
DOI: 10.1039/B002653K
Citation: J. Chem. Soc., Dalton Trans., 2000,0, 2595-2598

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    Simple linear-chain cobalt phosphates

    A. Choudhury, S. Natarajan and C. N. R. Rao, J. Chem. Soc., Dalton Trans., 2000, 0, 2595
    DOI: 10.1039/B002653K

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