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Issue 5, 2000
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Synthesis and structural characterization of the first completely alkyl-substituted Ga–Sb Lewis acid–base adducts

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Abstract

The simple Lewis acid–base adducts (n-Bu)3Ga(SbR3) (R = Et 1, n-Pr 2, i-Pr 3, t-Bu 4) and (t-Bu)3Ga(SbR3) (R = Et 5, n-Pr 6, i-Pr 7, t-Bu 8) were prepared by combination of n-Bu3Ga or t-Bu3Ga, respectively, with the corresponding trialkylstibanes in a 1∶1 molar ratio. 1–8 were fully characterized by multinuclear NMR (1H and 13C) and mass spectroscopy. In addition, the solid state structures of 5 and 7 were determined by single crystal X-ray diffraction studies.

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Supplementary files

Article information


Submitted
11 Nov 1999
Accepted
21 Jan 2000
First published
11 Feb 2000

J. Chem. Soc., Dalton Trans., 2000, 639-642
Article type
Paper

Synthesis and structural characterization of the first completely alkyl-substituted Ga–Sb Lewis acid–base adducts

S. Schulz and M. Nieger, J. Chem. Soc., Dalton Trans., 2000, 639
DOI: 10.1039/A908969A

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