Issue 22, 2000
From the journal:

Journal of the Chemical Society, Dalton Transactions

Alkali-metal complexes of a triazacyclononane-functionalized tetramethylcyclopentadienyl ligand †

Garth R. Giesbrecht,a   Andreas Gebauer,a   Alex Shafira  and  John Arnold*a  

* Corresponding authors

a Department of Chemistry, University of California, and the, Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley

Abstract

Reaction of (1,4-diisopropyl-1,4,7-triazacyclononane)Li with C5Me4HSiMe2Cl yields the new donor-functionalized ligand, [C5Me4SiMe2(tacn)]H; the alkali-metal salts [C5Me4SiMe2(tacn)]M (M = Li, Na, K) are obtained upon reaction with BuLi, NaN(SiMe3)2 or KN(SiMe3)2.

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Article information

DOI
https://doi.org/10.1039/B007075K
Article type
Communication
Submitted
28 Jun 2000
Accepted
22 Sep 2000
First published
19 Oct 2000

J. Chem. Soc., Dalton Trans., 2000, 4018-4020

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Alkali-metal complexes of a triazacyclononane-functionalized tetramethylcyclopentadienyl ligand

G. R. Giesbrecht, A. Gebauer, A. Shafir and J. Arnold, J. Chem. Soc., Dalton Trans., 2000, 4018 DOI: 10.1039/B007075K

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