Issue 22, 2000
From the journal:

Journal of the Chemical Society, Dalton Transactions

Transition metal complexes incorporating the BF2ligand formed by oxidative addition of the B–B bond in B2F4

Norman Lu,a   Nicholas C. Norman,a   A. Guy Orpen,a   Michael J. Quayle,a   Peter L. Timmsa  and  George R. Whittella  

a The University of Bristol, School of Chemistry, Cantock’s Close, Bristol, UK

Abstract

The reactions between B2F4 and the platinum and iridium complexes [Pt(PPh3)2(η-C2H4)], [Pt(dppb)(η-C2H4)] [dppb = 1,4-bis(diphenylphosphino)butane] and trans-[IrCl(CO)(PPh3)2] afforded the difluoroboryl complexes cis-[Pt(BF2)2(PPh3)2], cis-[Pt(BF2)2(dppb)] and fac-[Ir(BF2)3(CO)(PPh3)2] respectively all of which have been characterised by X-ray crystallography. The isoelectronic platinum dppb nitrito complex cis-[Pt(NO2)2(dppb)] has also been prepared and structurally characterised.

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Article information

DOI
https://doi.org/10.1039/B006535H
Article type
Paper
Submitted
09 Aug 2000
Accepted
19 Sep 2000
First published
26 Oct 2000

J. Chem. Soc., Dalton Trans., 2000, 4032-4037

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Transition metal complexes incorporating the BF2 ligand formed by oxidative addition of the B–B bond in B2F4

N. Lu, N. C. Norman, A. G. Orpen, M. J. Quayle, P. L. Timms and G. R. Whittell, J. Chem. Soc., Dalton Trans., 2000, 4032 DOI: 10.1039/B006535H

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